CATALYTIC-HYDROGENATION OF VEGETABLE-OILS I HYDROGENATION OF SOYBEAN OIL CATALYZED BY RH-COMPLEXES AND IR-COMPLEXES

被引：9

作者：

FRAGALE, C ^{[1
]}

GARGANO, M ^{[1
]}

GOMES, T ^{[1
]}

ROSSI, M ^{[1
]}

机构：

[1] UNIV BARI,INST IND AGR,I-70126 BARI,ITALY

来源：

JOURNAL OF THE AMERICAN OIL CHEMISTS SOCIETY | 1979年 / 56卷 / 04期

关键词：

D O I：

10.1007/BF02680187

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The rate and selectivity found for the hydrogenation reaction of soybean oil using a series of soluble rhodium and iridium-phosphine complexes can be correlated to the number of phosphine ligands coordinated to the metal. This study shows the possibility of obtaining a wide range of products by varying the reaction time and the catalyst composition. For example, a low stearate content can be obtained using IrCl(C8H12)PPh3, whereas a low double-bond conjugation can be obtained with |Rh(C8H12)(PPh3)2|BPh4. © 1979 The American Oil Chemists' Society.

引用

页码：498 / 502

页数：5

共 26 条

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