Photoelectron spectrometry of hydrogen sulfide

被引：36

作者：

Delwiche, J. ^{[1
]}

Natalis, P. ^{[1
]}

机构：

[1] Univ Liege, Inst Chim, Liege, Belgium

来源：

CHEMICAL PHYSICS LETTERS | 1970年 / 5卷 / 09期

关键词：

D O I：

10.1016/0009-2614(70)85047-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The high-resolution photoelectron spectrum of H2S shows mainly three vibrationally resolved bands corresponding to B-2(1), (2)A(1) and B-2(2) states of H3S+ with adiabatic ionization energies of 10.43, 12.76 and 14.91 eV and frequencies of 2476, 1113 and 2000 cm(-1) respectively. A sudden loss of vibrational structure in the second band is interpreted as due to a predissociation process leading to S+ ion formation.

引用

页码：564 / 566

页数：3

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