AN EFFICIENT SYNTHESIS OF 3,4-DIOXOCYCLOBUTENECARBOXYLATE DERIVATIVES

被引：40

作者：

CAMPS, F ^{[1
]}

LLEBARIA, A ^{[1
]}

MORETO, JM ^{[1
]}

RICART, S ^{[1
]}

VINAS, JM ^{[1
]}

机构：

[1] CSIC,CTR INVEST DESENVOLUPAMENT,DEPT QUIM ORGAN BIOL,JORDI GIRONA 18-26,E-08034 BARCELONA,SPAIN

来源：

TETRAHEDRON LETTERS | 1990年 / 31卷 / 17期

关键词：

D O I：

10.1016/S0040-4039(00)97394-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkynylalkoxycarbene metal complexes react readily with tetraalkoxyethylenes to give the corresponding [2 + 2] cycloadducts in high yields. From these adducts the title compounds were obtained by DMSO oxidation and final hydrolysis of the acetal groups. © 1990.

引用

页码：2479 / 2482

页数：4

共 16 条

[1] SYNTHESIS AND REACTIVITY OF COMPOUNDS WITH CYCLOBUTANE RINGS(S) .10. SYNTHESES OF SQUARIC ACID, ITS MONOORTHOESTERS, AND RELATED DERIVATIVES VIA [2 + 2] CYCLOADDITIONS OF TETRAALKOXYETHYLENES WITH HETEROSUBSTITUTED KETENES
BELLUS, D
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (08) : 1208 - 1211
[2] SYNTHESES OF MONILIFORMIN, A MYCOTOXINE WITH A CYCLOBUTENEDIONE STRUCTURE
BELLUS, D
FISCHER, H
GREUTER, H
MARTIN, P
[J]. HELVETICA CHIMICA ACTA, 1978, 61 (05) : 1784 - 1813
[3] CYCLOADDITION OF (TRIMETHYLSILYL)KETENE WITH TETRAALKOXYETHYLENES
BRADY, WT
SAIDI, K
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (04) : 727 - 729
[4] REACTION OF ETHYL DIETHOXYACRYLATE WITH ALKYNYLALKOXYCARBENE METAL (CR,W) COMPLEXES - NEW PROCEDURE FOR PREPARATION OF 6-ETHOXY-2H-PYRONES
CAMPS, F
MORETO, JM
RICART, S
VINAS, JM
MOLINS, E
MIRAVITLLES, C
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (20) : 1560 - 1562
[5] CARBENE COMPLEXES IN ORGANIC-SYNTHESIS
DOTZ, KH
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (08): : 587 - 608
[6] THE CHROMIUM AND TUNGSTEN PENTACARBONYL GROUPS AS REACTIVITY AUXILIARIES IN [2 + 2] CYCLO-ADDITIONS
FARON, KL
WULFF, WD
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (26) : 8727 - 8729
[7] INFRARED DYES FOR OPTICAL STORAGE
JIPSON, VB
JONES, CR
[J]. JOURNAL OF VACUUM SCIENCE & TECHNOLOGY, 1981, 18 (01): : 105 - 109
[8] CYCLOBUTENEDIONES AS PRECURSORS TO QUINONES AND CYCLOPENTENONES
LIEBESKIND, LS
[J]. TETRAHEDRON, 1989, 45 (10) : 3053 - 3060
[9] OOMS PHJ, 1975, SYNTHESIS-STUTTGART, P639
[10] OOMS PHJ, 1975, SYNTHESIS-STUTTGART, P260

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