EXCESS-ENTHALPIES OF NONAN-1-OL AND UNDECAN-1-OL WITH OCTANE AT HIGH DILUTIONS AND AT 298.15-K

被引：17

作者：

DOMANSKA, U ^{[1
]}

DOMANSKI, K ^{[1
]}

KLOFUTAR, C ^{[1
]}

PALJK, S ^{[1
]}

机构：

[1] E KARDELJ UNIV LJUBLJANA,J STEFAN INST,YU-61000 LJUBLJANA,YUGOSLAVIA

来源：

THERMOCHIMICA ACTA | 1990年 / 164卷

关键词：

D O I：

10.1016/0040-6031(90)80439-6

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Heats of mixing at high dilutions were determined for binary systems consisting of nonan-1-ol or undecan-1-ol and n-octane at 298.15 K. Partial molar heats of mixing at infinite dilution, giving approximate values of hydrogen bonding energies in alcohols, were determined by extrapolation of the experimental data to zero concentrations of the alcohols (x1 = 0). The results are correlated by means of polynomials, the UNIQUAC and the UNIQUAC associated-solution models. The ability of these equations to represent the thermodynamic functions of dilute mixtures of alkan-1-ols in n-alkanes at 298.15 K is discussed. © 1990.

引用

页码：227 / 236

页数：10

共 34 条

[1] STATISTICAL THERMODYNAMICS OF LIQUID-MIXTURES - NEW EXPRESSION FOR EXCESS GIBBS ENERGY OF PARTLY OR COMPLETELY MISCIBLE SYSTEMS [J].

ABRAMS, DS ;

PRAUSNITZ, JM .

AICHE JOURNAL, 1975, 21 (01) :116-128

[2]

BELLEMANS A, 1976, ROCZ CHEM, V50, P1749

[3] EXCESS ISOBARIC HEAT-CAPACITIES OF SOME BINARY-MIXTURES - (A C5-ALKANOL + NORMAL-HEPTANE) AT 298.15-K [J].

BENSON, GC ;

DARCY, PJ .

JOURNAL OF CHEMICAL THERMODYNAMICS, 1986, 18 (05) :493-498

[4] A CONTINUOUS LINEAR ASSOCIATION MODEL FOR DETERMINING THE ENTHALPY OF HYDROGEN-BOND FORMATION AND THE EQUILIBRIUM ASSOCIATION CONSTANT FOR PURE HYDROGEN-BONDED LIQUIDS [J].

BRANDANI, V .

FLUID PHASE EQUILIBRIA, 1983, 12 (1-2) :87-104

[5] HEATS OF MIXING .V. SYSTEMS OF N-ALCOHOLS WITH N-HEXANE [J].

BROWN, I ;

SMITH, F ;

FOCK, W .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1964, 17 (10) :1106-&

[6] SELF-ASSOCIATION OF ALCOHOLS IN INERT SOLVENTS - APPARENT HEAT-CAPACITIES AND VOLUMES OF LINEAR ALCOHOLS IN HYDROCARBONS [J].

COSTAS, M ;

PATTERSON, D .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1985, 81 :635-654

[7]

DREIFUS DW, 1971, T FARADAY SOC, V64, P631

[8] DETERMINATION OF ASSOCIATION CONSTANTS FOR ALCOHOLS BASED ON ETHERS AS HOMOMORPHS [J].

HOFMAN, T ;

NAGATA, I .

FLUID PHASE EQUILIBRIA, 1986, 25 (02) :113-128

[9] THERMODYNAMICS OF AGGREGATION OF TRI-NORMAL-OCTYLAMMONIUM HALIDES IN BENZENE SOLUTIONS [J].

KLOFUTAR, C ;

PALJK, S .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1981, 77 :2705-2716

[10] HEATS OF SOLUTION OF 1-NONANOL AND 1-UNDECANOL IN NORMAL-HEXANE, NORMAL-HEPTANE, NORMAL-DECANE AND NORMAL-HEXADECANE AT 298.15-K [J].

KLOFUTAR, C ;

PALJK, S ;

DOMANSKA, U .

THERMOCHIMICA ACTA, 1990, 158 (02) :301-315

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