SUBSTITUENT EFFECTS ON THE BENZYL GROUPS IN SOMMELET-HAUSER REARRANGEMENT

被引：16

作者：

TANAKA, T ^{[1
]}

SHIRAI, N ^{[1
]}

SATO, Y ^{[1
]}

机构：

[1] NAGOYA CITY UNIV, FAC PHARMACEUT SCI, TANABE DORI, MIZUHO KU, NAGOYA, AICHI 467, JAPAN

来源：

CHEMICAL & PHARMACEUTICAL BULLETIN | 1992年 / 40卷 / 02期

关键词：

YLIDE; SOMMELET-HAUSER REARRANGEMENT; DESILYLATION; FLUORIDE; SIGMATROPIC REARRANGEMENT; SUBSTITUENT EFFECT;

D O I：

10.1248/cpb.40.518

中图分类号：

R914 [药物化学];

学科分类号：

100701 ;

摘要：

The effects of substituents (MeO, Me, H, Br, CN, NO2) of the benzyl groups in the Sommelet-Hauser rearrangement of N,N-bis(substituted benzyl)-N-methyl(trimethylsilyl)methylammonium halides with cesium fluoride in N,N-dimethylformamide were examined.

引用

页码：518 / 520

页数：3

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