LIGAND-INDUCED DECOMPOSITION OF DODECACARBONYLTRIRUTHENIUM WITH DI-TERT-BUTYLPHOSPHINE - SYNTHESIS, CRYSTAL-STRUCTURE AND STRUCTURAL DYNAMICS OF HRU2(CO)4(PTBU2)(HPTBU2)2

被引：11

作者：

BOTTCHER, HC

RHEINWALD, G

STOECKLIEVANS, H

SUSSFINK, G

WALTHER, B

机构：

[1] UNIV NEUCHATEL,INST CHIM,AVE BELLEVAUX 51,CH-2000 NEUCHATEL,SWITZERLAND

[2] MARTIN LUTHER UNIV HALLE WITTENBERG,FACHBEREICH CHEM,D-06120 HALLE,GERMANY

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 469卷 / 02期

关键词：

PHOSPHORUS; RUTHENIUM; CLUSTER;

D O I：

10.1016/0022-328X(94)88069-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of RU3(CO)12 with HP(t)Bu2 leads to the complexes Ru3(CO)9(HP(t)Bu2)3 (1), HRU2(CO)4(PtBu2)(HPtBu2)2 (2) and Ru(CO)3(HPtBu)2)2 (3). The unsaturated dinuclear complex 2 reversibly takes up carbon monoxide to give the coordinatively saturated compound HRu2(CO)6(PtBU2)(HPtBu2) (4). The molecular structure of 2 has been established by single-crystal X-ray structure analysis; the solid-state structure differs from that in solution.

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收藏

页码：163 / 168

页数：6

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