HOMOGENEOUS BENZYLIC OXIDATION CATALYSED BY SOME COMPLEXES OF PLATINUM GROUP

被引：30

作者：

BLUM, J

BECKER, JY

ROSENMAN, H

BERGMANN, ED

机构：

[1] Department of Organic Chemistry, Hebrew University, Jerusalem

来源：

JOURNAL OF THE CHEMICAL SOCIETY B-PHYSICAL ORGANIC | 1969年 / 08期

关键词：

D O I：

10.1039/j29690001000

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The autoxidation of ethylbenzene and related compounds in the presence of a number of organic compounds of Rh, Ru, Pt, Ir, and Pd is investigated: RhCl(PPh3)3 is found to be a most effective catalyst in this reaction, whilst the application of RuCl2(PPh3) 3 is limited to the oxidation of non-halogenated alkylarenes and requires the addition of polyhalogenoalkane as co-catalyst. The reaction mechanism is discussed.

引用

页码：1000 / &

共 28 条

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