PHOTOIONIZATION AND MASS-SELECTED PHOTODISSOCIATION OF TELLURIUM CLUSTERS

被引:49
作者
WILLEY, KF [1 ]
CHENG, PY [1 ]
TAYLOR, TG [1 ]
BISHOP, MB [1 ]
DUNCAN, MA [1 ]
机构
[1] UNIV GEORGIA,SCH CHEM SCI,DEPT CHEM,ATHENS,GA 30602
关键词
D O I
10.1021/j100367a061
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Tellurium clusters in the size range of 2-20 atoms are produced by laser vaporization in a pulsed-nozzle molecular beam source. Cluster distributions are characterized by direct sampling of cations condensed from the vaporization plasma and by photoionization of neutral species. Mass-selected clusters are studied with ultraviolet laser photodissociation. Fragmentation preferentially produces the molecular species Te4, Te2+, Te5+, and Te7+. © 1990 American Chemical Society.
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页码:1544 / 1549
页数:6
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