SELECTIVITY OF THE CARBONYLATION OF STYRENE BY CATIONIC PALLADIUM COMPLEXES

被引：76

作者：

PISANO, C ^{[1
]}

MEZZETTI, A ^{[1
]}

CONSIGLIO, G ^{[1
]}

机构：

[1] SWISS FED INST TECHNOL,DEPT IND & ENGN CHEM,CH-8092 ZURICH,SWITZERLAND

来源：

ORGANOMETALLICS | 1992年 / 11卷 / 01期

关键词：

D O I：

10.1021/om00037a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Pd(CH3CN)4][BF4]2 modified with different nitrogen and mono- or bidentate phosphorus ligands catalyzes the formation of (E)-1,5-diphenylpent-1-en-3-one from styrene and carbon monoxide; the use of hybrid ligands, particularly phosphine thioethers, switches the regioselectivity to bring about a largely selective formation of (E)-1,4-diphenylpent-1-en-3-one.

引用

页码：20 / 22

页数：3

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