CARBOCYCLIC RING EXPANSION REACTIONS VIA FREE-RADICAL PATHWAYS .3.

被引:26
作者
BALDWIN, JE
ADLINGTON, RM
SINGH, R
机构
[1] The Dyson Perrins Laboratory, University of Oxford, Oxford, OX1 3QY, South Parks Road
关键词
FREE RADICAL; ENOLATE; RING EXPANSION; ALKOXY RADICAL;
D O I
10.1016/0040-4020(92)85014-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The free radical ring expansion methodology recently described1, leading to the formation of medium sized ring ketones from cyclohexanone precursors has been applied to different side chains and ring sizes. In addition precursors based on lactone rings have been prepared and subjected to radical forming reaction conditions.
引用
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页码:3385 / 3412
页数:28
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