FACILE 1,3-HYDRIDE TRANSFER IN A CYCLOHEPTYL CATION

被引：12

作者：

ANGLE, SR

MATTSONARNAIZ, HL

机构：

[1] Department of Chemistry, University of California, Riverside

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 25期

关键词：

D O I：

10.1021/ja00051a009

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The intramolecular addition of a benzylic cation to a vinylsilane was studied. The benzylic (methoxyethoxy)methyl ether 1 was shown to undergo an unusual cyclization to afford a substituted cycloheptene (12) upon treatment with a Lewis acid. Following cyclization, the molecule undergoes a formal 1,3-hydride shift, followed by elimination to give styrene 12.

引用

页码：9782 / 9786

页数：5

共 27 条

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