SYNTHESIS, STRUCTURE AND FILM-FORMING PROPERTIES OF POLY(BUTYL METHACRYLATE) POLY(METHACRYLIC ACID) CORE-SHELL LATEX

被引：64

作者：

KIM, HB

WANG, YC

WINNIK, MA

机构：

[1] UNIV TORONTO, DEPT CHEM, TORONTO M5S 1A1, ONTARIO, CANADA

[2] HOKKAIDO UNIV, FAC ENGN, DEPT CHEM, SAPPORO, HOKKAIDO 060, JAPAN

[3] EASTMAN KODAK CO, ROCHESTER, NY 14650 USA

来源：

POLYMER | 1994年 / 35卷 / 08期

基金：

加拿大自然科学与工程研究理事会;

关键词：

POLY(BUTYL METHACRYLATE); POLY(METHACRYLIC ACID); CORE-SHELL LATEX;

D O I：

10.1016/0032-3861(94)90856-7

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The preparation and characterization are described of a series of core-shell poly(butyl methacrylate) latex particles containing varying amounts of carboxylic acid groups. Matched pairs of particles, labelled with either donor (phenanthrene) or acceptor (anthracene) groups, were prepared by three-stage emulsion polymerization under monomer-starved conditions in which varying amounts of methacrylic acid were introduced into the third-stage polymerization. Films were prepared from the latex. The rate of polymer interdiffusion in the films, as followed by energy transfer measurements, decreased as the carboxyl content of the latex shell increased.

引用

页码：1779 / 1786

页数：8

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