KINETICS OF THE CATALYTIC CRACKING OF PARAFFINS AT VERY SHORT TIMES ON STREAM

被引:24
作者
CORMA, A [1 ]
MIGUEL, PJ [1 ]
ORCHILLES, AV [1 ]
机构
[1] UNIV VALENCIA, DEPT INGN QUIM, E-46100 BURJASSOT, SPAIN
关键词
D O I
10.1006/jcat.1994.1007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The kinetics for the cracking of n-heptane, n-decane, n-dodecane and n-tetradecane has been investigated in a reaction system in which conversion and yields can be measured at times on stream below 10 sec. Under these experimental conditions the influence of the adsorption terms in the kinetic expression is negligible. The catalyst decay is better represented by a conversion-dependent time on stream function. © 1994 Academic Press, Inc.
引用
收藏
页码:58 / 64
页数:7
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