OXONIUM ION INTERMEDIATES IN REARRANGEMENT OF THEBAINE

被引：6

作者：

CHANNON, RT

KIRBY, GW

MASSEY, SR

机构：

[1] Chemistry Department, University of Technology, Loughborough

来源：

JOURNAL OF THE CHEMICAL SOCIETY C-ORGANIC | 1969年 / 09期

关键词：

D O I：

10.1039/j39690001215

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rearrangement of thebaine and its metho-salts in trifluoroacetic acid has been shown to involve red oxonium ion intermediates. Quaternary salts of 7,8-dehydrometathebainone have been isolated and a convenient preparation of neodihydrothebaine from thebaine has been devised.

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页码：1215 / &

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