THERMOCHEMICAL EFFECTS IN HEXAFLUOROETHANE (FREON-116) MODIFIED ARGON INDUCTIVELY COUPLED PLASMAS

被引：15

作者：

EBDON, L

GOODALL, P

机构：

[1] Plymouth Analytical Chemistry Research Unit, Department of Environmental Sciences, University of Plymouth, Plymouth, PL4 8AA, Drake Circus

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 1992年 / 47卷 / 11期

关键词：

D O I：

10.1016/0584-8547(92)80116-X

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Hexafluoroethane (Freon 116), added to the argon nebulizer gas, has been investigated as a potential volatilization aid for refractory materials in slurry nebulization inductively coupled plasma atomic emission spectrometry (ICP-AES). The introduction of Freon 116 resulted in apparently unusual plasma spectrochemistry, which yielded non-linear calibration curves. These were attributed to classical mass action buffering involving highly stable metal fluoride species. This dictated against the use of Freon 116 as a volatilization aid in slurry nebulization ICP-AES.

引用

页码：1247 / 1257

页数：11

共 27 条

[1] DIRECT ATOMIC SPECTROMETRIC ANALYSIS BY SLURRY ATOMIZATION .8. FLOW-INJECTION INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION-SPECTROMETRY [J].

AMBROSE, AJ ;

EBDON, L ;

FOULKES, ME ;

JONES, P .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1989, 4 (02) :219-222

[2]

Barin I., 1973, THERMOCHEMICAL PROPE

[3]

BARNES RM, 1983, SPECTROCHIM ACTA B, V38, P191

[4] DIRECT ANALYSIS OF SOIL SUSPENSIONS BY INDUCTIVELY COUPLED PLASMA-ATOMIC EMISSION-SPECTROMETRY FOR DETERMINATION OF TOTAL METALS [J].

DICK, WA ;

PAGE, JR ;

JEWELL, KE .

SOIL SCIENCE, 1985, 139 (03) :211-218

[5] DIRECT ATOMIC SPECTROMETRIC ANALYSIS BY SLURRY ATOMIZATION .7. ANALYSIS OF COAL USING INDUCTIVELY COUPLED PLASMA MASS-SPECTROMETRY [J].

EBDON, L ;

FOULKES, ME ;

PARRY, HGM ;

TYE, CT .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1988, 3 (06) :753-761

[6] DIRECT ATOMIC SPECTROMETRIC ANALYSIS BY SLURRY ATOMIZATION .5. ANALYSIS OF KAOLIN USING INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION-SPECTROMETRY [J].

EBDON, L ;

COLLIER, AR .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1988, 3 (04) :557-561

[7] DIRECT ATOMIC SPECTROMETRIC ANALYSIS BY SLURRY ATOMIZATION .9. FUNDAMENTAL-STUDIES OF REFRACTORY SAMPLES [J].

EBDON, L ;

FOULKES, ME ;

HILL, S .

JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1990, 5 (01) :67-73

[8] PARTICLE-SIZE EFFECTS ON KAOLIN SLURRY ANALYSIS BY INDUCTIVELY COUPLED PLASMA-ATOMIC EMISSION-SPECTROMETRY [J].

EBDON, L ;

COLLIER, AR .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1988, 43 (4-5) :355-369

[9] NEBULIZATION OF SLURRIES AND SUSPENSIONS OF GEOLOGICAL-MATERIALS FOR INDUCTIVELY COUPLED PLASMA-ATOMIC EMISSION-SPECTROMETRY [J].

HALICZ, L ;

BRENNER, IB .

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY, 1987, 42 (1-2) :207-217

[10] THEORETICAL-EXAMINATION OF SOLUTE PARTICLE VAPORIZATION IN ANALYTICAL ATOMIC SPECTROMETRY [J].

HIEFTJE, GM ;

MILLER, RM ;

PAK, Y ;

WITTIG, EP .

ANALYTICAL CHEMISTRY, 1987, 59 (24) :2861-2872

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