EFFECT OF DISSOLVED ORGANIC-MATTER AND PH ON THE MIGRATION OF ZINC THROUGH RIVER BANK SEDIMENTS

被引:13
作者
BOURG, ACM [1 ]
DARMENDRAIL, D [1 ]
机构
[1] BUR RECH GEOL & MINIERES,NORD PAS CALAIS REG AGCY,F-59260 HELEMMES LILLE,FRANCE
关键词
ZINC; DISSOLVED ORGANIC MATTER; PH; SEDIMENTS; PERCOLATION;
D O I
10.1080/09593339209385199
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The migration of zinc through river bank sediments is studied in column experiments. Even when the initial dissolved zinc is low enough to prevent precipitation of zinc minerals in the column, adsorption processes strongly retard the transport of the metal with respect to water. Organic matter, when dissolved, can significantly increase the mobility of Zn. Small pH variations are as important as organic matter in the control of the solubility and transport of zinc. The adsorption of zinc seems to control, at least partially, the solubility of organic matter (most likely as ternary surface complexes of the form solid-Zn-organics). Dissolved organic matter and pH are therefore master variables for the understanding of zinc transport through river bank sediments.
引用
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页码:695 / 700
页数:6
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