MEDIUM-DEPENDENT TRAPPING OF DIAZOALKANE INTERMEDIATES DURING PHOTOLYSIS OF DIAZIRINES

被引：5

作者：

BENNETT, P

HARWOOD, LM

MACRO, J

MCGREGOR, A

机构：

[1] UNIV OXFORD,DYSON PERRINS LAB,OXFORD OX1 3QY,ENGLAND

[2] HORSELL GRAPH IND,LEEDS LS27 0QT,W YORKSHIRE,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 08期

关键词：

D O I：

10.1039/c39940000961

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photolysis of an intimate mixture of methyl(phenyl)diazirine and N-methylmaleimide in the absence of solvent permits the diazoalkane intermediate to be trapped, whereas the equivalent reaction in solution gives only cyclopropanated adducts.

引用

页码：961 / 962

页数：2

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