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POLYMER DYNAMICS .4. ZERO-FREQUENCY INTRINSIC VISCOSITY OF POLYMER MOLECULES WITH HYDRODYNAMIC INTERACTION AND EXCLUDED VOLUME

被引：39
作者：
HEARST, JE
BEALS, E
HARRIS, RA
机构：
[1] Department of Chemistry, University of California, Berkeley, CA
[2] Mathematics and Computing Section, Lawrence Radiation Laboratory, Berkeley, CA
来源：
JOURNAL OF CHEMICAL PHYSICS | 1968年 / 48卷 / 12期
关键词：
D O I：
10.1063/1.1668231
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The theory and model of Harris and Hears! has been extended to approximately include the effect of hydrodynamic interaction and excluded volume. The results agree in both the coil and rigid-rod limits with existing theories and experiment. The absence of a linear dependence of [ij] upon an appropriate power of the molecular weight introduces some doubt as to the validity of conventional methods of interpretation of viscosity data.
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页码：5371 / &
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