APPARENT MOLAL HEAT-CAPACITIES OF ORGANIC SOLUTES IN WATER .5. AMINOALCOHOLS, AMINOETHERS, DIAMINES, AND POLYETHERS

被引：11

作者：

CABANI, S ^{[1
]}

LOBO, ST ^{[1
]}

MATTEOLI, E ^{[1
]}

机构：

[1] CNR,CHIM QUANT & ENERGET MOLEC LAB,I-56100 PISA,ITALY

来源：

JOURNAL OF SOLUTION CHEMISTRY | 1979年 / 8卷 / 01期

关键词：

aminoalcohols; aminoethers; Apparent molal heat capacities; aqueous solutions; diamines; ethers; solute-water interactions;

D O I：

10.1007/BF00646804

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Apparent molal heat capacities of 20 organic uncharged compounds in aqueous solution have been determined at 25 and 40°C. The substances studied include mono- and polyfunctional ethers, and bifunctional open-chain compounds like aminoalcohols, aminoethers, and diamines. The results obtained support the presence of interaction between water and the hydrophilic groups -O-, -NH2, -NH-, and {Mathematical expression}, and evidence indicates that these interactions strongly depend on the molecular structure of the compound containing the functional group. © 1979 Plenum Publishing Corporation.

引用

页码：5 / 10

页数：6

共 18 条

[1] THERMODYNAMIC PROPERTIES OF ORGANIC-COMPOUNDS IN AQUEOUS-SOLUTION .2. APPARENT MOLAL HEAT-CAPACITIES OF PIPERIDINES, MORPHOLINES, AND PIPERAZINES [J].

CABANI, S ;

CONTI, G ;

MATTEOLI, E .

JOURNAL OF SOLUTION CHEMISTRY, 1976, 5 (02) :125-132

[2] PARTIAL MOLAL EXPANSIBILITIES OF ORGANIC-COMPOUNDS IN AQUEOUS-SOLUTION .1. ALCOHOLS AND ETHERS [J].

CABANI, S ;

CONTI, G ;

MATTEOLI, E .

JOURNAL OF SOLUTION CHEMISTRY, 1976, 5 (11) :751-763

[3] HEAT-CAPACITIES OF HYDRATION OF SATURATED UNCHARGED ORGANIC-COMPOUNDS AT 25-DEGREES-C [J].

CABANI, S ;

CONTI, G ;

MATTEOLI, E .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1978, 74 :2408-2417

[4] APPARENT MOLAL HEAT-CAPACITIES IN AQUEOUS-SOLUTION OF MOLECULES CONTAINING PEPTIDE LINKAGE - CYCLIC AND OPEN-CHAIN DIPEPTIDES [J].

CABANI, S ;

CONTI, G ;

MATTEOLI, E .

BIOPOLYMERS, 1977, 16 (02) :465-467

[5] APPARENT MOLAL HEAT-CAPACITIES OF ORGANIC-COMPOUNDS IN AQUEOUS SOLUTION .3. OMEGA-AMINO ACIDS AND RELATED COMPOUNDS [J].

CABANI, S ;

CONTI, G ;

MATTEOLI, E ;

TANI, A .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1977, 73 :476-486

[6] THERMODYNAMIC PROPERTIES OF ORGANIC COMPOUNDS IN AQUEOUS-SOLUTIONS - APPARENT MOLAL HEAT-CAPACITIES OF AMINES AND ETHERS [J].

CABANI, S ;

CONTI, G ;

MARTINEL.A ;

MATTEOLI, E .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1973, 69 (12) :2112-2123

[7] VOLUME CHANGES IN PROTON IONIZATION OF AMINES IN WATER .2. AMINO-ALCOHOLS, AMINO ETHERS, AND DIAMINES [J].

CABANI, S ;

MOLLICA, V ;

LEPORI, L ;

LOBO, ST .

JOURNAL OF PHYSICAL CHEMISTRY, 1977, 81 (10) :987-993

[8]

CABANI S, J CHEM SOC F1

[9]

FRANKS F, 1973, WATER COMPREHENSIVE, V2, P323

[10] ADDITIVITY SCHEMES PERMITTING ESTIMATION OF PARTIAL MOLAR HEAT-CAPACITIES OF ORGANIC-COMPOUNDS IN AQUEOUS-SOLUTION [J].

GUTHRIE, JP .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1977, 55 (21) :3700-3706

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