[(ME3SN-IV)4FE-II(CN)6.4H2O]INFINITY, AN ORGANOTIN BERLIN-BLUE ANALOG WITH COORDINATIVE O-H...N HYDROGEN-BONDS

被引：28

作者：

BEHRENS, U

BRIMAH, AK

FISCHER, RD

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1991年 / 411卷 / 03期

关键词：

D O I：

10.1016/0022-328X(91)83038-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The lattice of the new organometallic coordination polymer: [(Me3Sn)4Fe(CN)6.4H2O] infinity is built up of nonlinear [GRAPHICS] and [GRAPHICS] chains (O...O: 2.628(11) angstrom) which are interlinked by the coordinated and ''zeolitic'' H2O molecules, respectively, via six (comparatively weak) O-H...N hydrogen bonds O...N: 2.972(8) and 3.052(8) angstrom). Orthorhombic single-crystal, space group Cmca, a 17.064(2), b 18.534(2), c 11.586(1) angstrom; R = 0.054 (R(w) = 0.059).

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页码：325 / 330

页数：6

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