Intramolecular Addition In Hex-5-enyl, Hept-6-enyl, and Oct-7-enyl Radicals

被引：173

作者：

Beckwith, Athelstan L. J. ^{[1
]}

Moad, Graeme ^{[1
]}

机构：

[1] Univ Adelaide, Dept Organ Chem, Adelaide, SA 5001, Australia

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1974年 / 12期

关键词：

D O I：

10.1039/c39740000472

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Each of the radicals, hex-5-enyl, hept-6-enyl, and oct-7-enyl, undergoes intramolecular addition preferentially in that direction which affords the cyclo-alkylcarbinyl radical, because both enthalpy and entropy factors are more favourable; an approximate rate constant for 1,5-hydrogen atom transfer in hept-6-enyl radical has been determined.

引用

页码：472 / 473

页数：2

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