Palladium-catalyzed allylic amination of allylic alcohols with tin(II) chloride and triethylamine

被引：59

作者：

Masuyama, Y

Kagawa, M

Kurusu, Y

机构：

来源：

CHEMISTRY LETTERS | 1995年 / 12期

关键词：

D O I：

10.1246/cl.1995.1121

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allylic alcohols caused allylic amination with primary or secondary amines in the presence of a catalytic amount of Pd(PPh(3))(4) and a stoichiometric amount of tin(II) chloride in THF at 50 degrees C to produce the corresponding allylic amines regioselectively.

引用

收藏

页码：1121 / 1122

页数：2

相关论文

共 12 条

[1]

ATKINS KE, 1970, TETRAHEDRON LETT, P3821

[2] ALKYLATION OF ACTIVE METHYLENE-COMPOUNDS BY ALLYLIC ALCOHOLS USING TETRAKIS(TRIPHENYLPHOSPHINE)PALLADIUM(0) CATALYSTS [J].

BERGBREITER, DE ;

WEATHERFORD, DA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (13) :883-884

[3] SYNTHESIS OF ALPHA-AMINO-ACIDS BY ALKYLATION OF DIETHYL ACETAMIDOMALONATE IN THE PRESENCE OF PALLADIUM COMPLEXES [J].

HAUDEGOND, JP ;

CHAUVIN, Y ;

COMMEREUC, D .

JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (17) :3063-3065

[4] SYNTHESIS OF N-PROTECTED AMINO ESTERS VIA PALLADIUM-CATALYZED ALLYLIC SUBSTITUTION [J].

JUMNAH, R ;

WILLIAMS, JMJ ;

WILLIAMS, AC .

TETRAHEDRON LETTERS, 1993, 34 (41) :6619-6622

[5] PALLADIUM AND ARSENIC(III) OXIDE-CATALYZED ALLYLIC ALKYLATION BY ALLYLIC ALCOHOLS UNDER NEUTRAL CONDITIONS [J].

LU, XY ;

LU, L ;

SUN, JH .

JOURNAL OF MOLECULAR CATALYSIS, 1987, 41 (1-2) :245-251

[6] PALLADIUM-CATALYZED ALLYLIC ALKYLATION OF CARBONUCLEOPHILES WITH ALLYLIC BORATES OR ALLYLIC ALCOHOLS AND BORON-OXIDE UNDER NEUTRAL CONDITIONS [J].

LU, XY ;

JIANG, XH ;

TAO, XC .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1988, 344 (01) :109-118

[7]

MSUYAMA Y, 1994, ADV METAL ORGANIC CH, V3, P255

[8]

SAKAMOTO M, 1994, 41ST S ORG CHEM JAP

[9] PALLADIUM-CATALYZED CARBONYL ALLYLATION BY ALLYLIC ALCOHOLS WITH SNCL2 [J].

TAKAHARA, JP ;

MASUYAMA, Y ;

KURUSU, Y .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (07) :2577-2586

[10] PALLADIUM(0)-CATALYZED ALLYLIC ALKYLATION AND AMINATION OF ALLYLIC PHOSPHATES [J].

TANIGAWA, Y ;

NISHIMURA, K ;

KAWASAKI, A ;

MURAHASHI, SI .

TETRAHEDRON LETTERS, 1982, 23 (52) :5549-5552