SULFUR SUBSTITUTED ORGANOTIN COMPOUNDS .9. CRYSTAL AND MOLECULAR-STRUCTURE AND REACTIONS OF [(PARA-CHLOROPHENYLTHIO)METHYL]TRICYCLOHEXYLSTANNANE

被引：14

作者：

COX, PJ

DOIDGEHARRISON, SMSV

NOWELL, IW

HOWIE, RA

RANDALL, AP

WARDELL, JL

机构：

[1] UNIV ABERDEEN,DEPT CHEM,MESTON WALK,ABERDEEN AB9 2UE,SCOTLAND

[2] ROBERT GORDONS INST TECHNOL,SCH PHARM,ABERDEEN AB1 1FR,SCOTLAND

[3] ROBERT GORDONS INST TECHNOL,SCH APPL SCI,ABERDEEN AB1 1HG,SCOTLAND

来源：

INORGANICA CHIMICA ACTA | 1990年 / 172卷 / 02期

关键词：

D O I：

10.1016/S0020-1693(00)80860-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structure of [(p-chlorophenylthio)methyl]tricyclohexylstannane (II) has been determined. In the two independent molecules of monoclinic II there are slightly distorted tetrahedral geometries about tin with intramolecular SnS distances of 3.29(1) and 3.26(1) Å. Compound II reacts with N-bromosuccinimide, I2, Pb(OAc)4 or CF3CO2H to give XCH2SC6H4Cl-p (X = Br, I, AcO or H) and the appropriate tricyclohexyltin species; II is less reactive than Cy3SnCH2SeC6H4Cl-p towards I2. Oxidative cleavage of II by m-ClC6H4CO·O·OH provides mainly CH3S(O)C6H4Cl-p. The absorption maximum for the charge transfer complex of II and (NC)2CC(CN)2 is reported. © 1990.

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页码：225 / 232

页数：8

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