SYNTHESIS OF [2-((DIMETHYLAMINO)METHYL)PHENYL]-(2-NITROPHENYL)GOLD(III) COMPLEXES

被引：24

作者：

VICENTE, J

BERMUDEZ, MD

CHICOTE, MT

SANCHEZSANTANO, MJ

机构：

[1] Departamento de Química Inorgánica, Facultad de Ciencias Química, Universidad de Murcia, Campus de Espinardo

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 381卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)80121-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Au(2-C6H4CH2NMe2)Cl 2] reacts with [Hg(2-C6H4NO2)2] and (Me4N)Cl (2/1/2) to give [Au(2-C6H4CH2NMe2)(2-C6 H4NO2)Cl] (I). Metathetical reactions of I with AgAc (Ac = OOCCH3), KBr or KI give complexes [Au(2-C6H4CH2NMe2)(2-C6 H4NO2)X] (X = Ac (II), Br (III), I (IV)), all of which are obtained as mixtures of two isomers. The reaction of I with PPh3 (1/1) gives [Au(2-C6H4CH2NMe2)(2-C6 H4NO2)Cl(PPh3)] (V), which reacts with NaClO4 (1/1) to give [Au(2-C6H4CH2NMe2)(2-C6 H4NO2)(PPh3)]ClO4 (VI). This can also be obtained directly by treating I with PPh3 and NaClO4 (1/1/1). A similar method (I + L + AgClO4) can be used to prepare [Au(2-C6H4CH2NMe2)(2-C6 H4NO2)-(py)]ClO4 (py = pyridine) (VII). © 1990.

引用

页码：285 / 292

页数：8

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