CYCLOADDITION OF ZIRCONACYCLOPENTADIENES TO ALKYNES USING COPPER-SALTS - FORMATION OF BENZENE-DERIVATIVES

被引：98

作者：

TAKAHASHI, T ^{[1
]}

KOTORA, M ^{[1
]}

XI, ZF ^{[1
]}

机构：

[1] GRAD UNIV ADV STUDIES,OKAZAKI,AICHI 444,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 03期

关键词：

D O I：

10.1039/c39950000361

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of zirconacyclopentadienes with alkynes such as dimethyl acetylenedicarboxylate gives benzene derivatives in the presence of CuCl/LiCl.

引用

页码：361 / 362

页数：2

共 15 条

[1]

[Anonymous], TETRAHEDRON LETT

[2] THE TRIMETHYLPHOSPHINE ADDUCT OF THE ZIRCONOCENE BENZYNE COMPLEX - SYNTHESIS, REACTIONS, AND X-RAY CRYSTAL-STRUCTURE [J].

BUCHWALD, SL ;

WATSON, BT ;

HUFFMAN, JC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) :7411-7413

[3] SELECTIVE, ZIRCONIUM-MEDIATED CROSS-COUPLING OF ALKYNES - SYNTHESIS OF ISOMERICALLY PURE 1,3-DIENES AND 1,4-DIIODO 1,3-DIENES [J].

BUCHWALD, SL ;

NIELSEN, RB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (08) :2870-2874

[4]

COLLMAN JP, 1987, PRINCIPLES APPLICATI

[5] THE CHEMISTRY OF TITANACYCLOPENTADIENE RINGS SUPPORTED BY 2,6-DIPHENYLPHENOXIDE LIGATION - STOICHIOMETRIC AND CATALYTIC REACTIVITY [J].

HILL, JE ;

BALAICH, G ;

FANWICK, PE ;

ROTHWELL, IP .

ORGANOMETALLICS, 1993, 12 (08) :2911-2924

[6]

KASAI K, 1994, J CHEM SOC CHEM COMM, P2693

[7] METAL-PROMOTED CYCLIZATION .11. REACTION OF ZIRCONOCENE DICHLORIDE WITH ALKYLLITHIUMS OR ALKYL GRIGNARD-REAGENTS AS A CONVENIENT METHOD FOR GENERATING A ZIRCONOCENE EQUIVALANT AND ITS USE IN ZIRCONIUM-PROMOTED CYCLIZATION OF ALKENES, ALKYNES, DIENES, ENYNES, AND DIYNES [J].

NEGISHI, E ;

CEDERBAUM, FE ;

TAKAHASHI, T .

TETRAHEDRON LETTERS, 1986, 27 (25) :2829-2832

[8] TRANSITION-METAL-MEDIATED CYCLO-ADDITION REACTIONS OF ALKYNES IN ORGANIC-SYNTHESIS [J].

SCHORE, NE .

CHEMICAL REVIEWS, 1988, 88 (07) :1081-1119

[9] FACILE CLEAVAGE OF THE C-BETA-C-BETA'-BOND OF ZIRCONACYCLOPENTENES - CONVENIENT METHOD FOR SELECTIVELY COUPLING ALKYNES WITH ALKYNES, NITRILES, AND ALDEHYDES [J].

TAKAHASHI, T ;

KAGEYAMA, M ;

DENISOV, V ;

HARA, R ;

NEGISHI, E .

TETRAHEDRON LETTERS, 1993, 34 (04) :687-690

[10] COPPER-CATALYZED C-C BOND FORMATION REACTION OF ALLYLZIRCONATION PRODUCTS OF ALKYNES [J].

TAKAHASHI, T ;

KOTORA, M ;

KASAI, K ;

SUZUKI, N .

TETRAHEDRON LETTERS, 1994, 35 (31) :5685-5688

← 1 2 →