PREPARATION AND ENANTIOMER RECOGNITION BEHAVIOR OF AZOPHENOLIC CROWN-ETHERS CONTAINING CIS-CYCLOHEXANE-1,2-DIOL AS THE CHIRAL CENTER

被引：32

作者：

NAEMURA, K ^{[1
]}

TAKEUCHI, S ^{[1
]}

HIROSE, K ^{[1
]}

TOBE, Y ^{[1
]}

KANEDA, T ^{[1
]}

SAKATA, Y ^{[1
]}

机构：

[1] OSAKA UNIV,INST SCI & IND RES,IBARAKI,OSAKA 567,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1995年 / 03期

基金：

英国自然环境研究理事会;

关键词：

D O I：

10.1039/p19950000213

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Both enantiomers of the azophenolic crown ether 1 incorporating the cis-cyclohexane 1,2-diol residue as the chiral centre have been prepared in;enantiomerically pure forms and the chiral recognition behaviour towards 2-aminoethanols and ethylamines has been examined. The observed enantiomer selectivities of the crown ether 1 in complexation with racemic amines have been interpreted on the basis of CPK molecular model examination of the diastereoisomeric complexes.

引用

页码：213 / 219

页数：7

共 26 条

[1] A SPECTROPHOTOMETRIC INVESTIGATION OF THE INTERACTION OF IODINE WITH AROMATIC HYDROCARBONS [J].