NEW GERMANIUM TETRACOBALT CARBONYL - GECO4(CO)14

被引：9

作者：

GERLACH, RF

MACKAY, KM

NICHOLSON, BK

机构：

[1] School of Science, University of Waikato, Hamilton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 178卷 / 02期

关键词：

D O I：

10.1016/S0022-328X(00)94240-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The room-temperature reaction of NaCo(CO)4 with halogermanes, or Co2(CO)8 with GeH4, gives GeCo4(CO)14 which is assigned a Ge[Co2(CO)7]2 structure on infrared evidence. This new species eliminates one CO at 50°C to give (CO)4CoGeCO3(CO)9 and adds further CO(CO)4- to give anionic [GeCo6(CO)n]2-. © 1979.

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页码：C30 / C32

页数：3

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