STEREOSELECTIVE PARTIAL HYDROGENATION OF THE TRIPLE BOND IN METHYL 2-ETHYL-6,6-DIMETHYLHEPT-2-EN-4-YNOATE - A COMPARISON OF LINDLAR AND MONTMORILLONITE CATALYSTS

被引：8

作者：

NIKLES, M ^{[1
]}

BUR, D ^{[1
]}

SEQUIN, U ^{[1
]}

机构：

[1] UNIV BASEL,INST ORGAN CHEM,ST JOHANNS RING 19,CH-4056 BASEL,SWITZERLAND

来源：

TETRAHEDRON | 1990年 / 46卷 / 05期

关键词：

D O I：

10.1016/S0040-4020(01)81966-9

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Lindlar catalyst proved to be superior to the montmorillonite-PdII catalyst in the stereoselective partial hydrogenation of a tert-butyl substituted, conjugated enynoate system inasmuch as a better yield of the product with the double bond was obtained and less overhydrogenation occurred. © 1990.

引用

页码：1569 / 1578

页数：10

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