INSERTION OF NORBORNADIENE INTO THE ARYL PALLADIUM BOND - SYNTHESIS, STRUCTURE AND DYNAMICS OF INTRAMOLECULAR ETA-2-ARENE PALLADIUM SPECIES

被引：132

作者：

LI, CS ^{[1
]}

CHENG, CH ^{[1
]}

LIAO, FL ^{[1
]}

WANG, SL ^{[1
]}

机构：

[1] NATL TSING HUA UNIV,DEPT CHEM,HSINCHU 30043,TAIWAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 10期

关键词：

D O I：

10.1039/c39910000710

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A series of fluxional intramolecular eta-2-bound arene complexes, (C7H8Ar)PdI(PPh3), 1a-1d, and 2 may be isolated from the catalytic reactions of norbornadiene (or norbornene) with aryl iodides in the presence of Zn and PdCl2(PPh3)2 (eqn. 1) and their structures have been determined by X-ray crystallography and NMR spectroscopy.

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页码：710 / 712

页数：3

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