SYNTHESIS AND NONLINEAR-OPTICAL PROPERTIES OF SUBSTITUTED STYRYLPYRIDINIUM-MPS3 INTERCALATION COMPOUNDS (M = MN, CD)

被引：32

作者：

LACROIX, PG

LEMARINIER, AVV

CLEMENT, R

NAKATANI, K

DELAIRE, JA

机构：

[1] UNIV PARIS 11, CHIM INORGAN LAB, CNRS, URA 420, F-91405 ORSAY, FRANCE

[2] UNIV PARIS 11, EQUIPE ENS CACHAN, PHYS CHIM RAYONNEMENTS LAB, URA 75, F-91405 ORSAY, FRANCE

来源：

JOURNAL OF MATERIALS CHEMISTRY | 1993年 / 3卷 / 05期

关键词：

LAYERED MATERIAL; INTERCALATION; INSERTION; NONLINEAR OPTICAL MATERIAL; 2ND-HARMONIC GENERATION;

D O I：

10.1039/jm9930300499

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New intercalation compounds, M1-xPS3(G)2x(H2O)y (M = Mn, Cd) have been synthesized, where G denotes the 4-[4-(dimethylamino)-alpha-styryl]-1-methylpyridinium cationic chromophore. The non-linear optical properties of these materials were studied by the Kurtz powder technique. Second-harmonic generation has been evidenced, with an efficiency comparable to that of urea. This preliminary result shows that MPS3 layered host lattices can be envisaged for achieving spontaneous poling of cationic chromophores.

引用

页码：499 / 503

页数：5

共 51 条

[1] MOLECULAR DISPOSITION OF SODIUM PARA-NITROPHENOLATE IN CAVITIES OF CYCLOHEPTAAMYLOSE AND CYCLOHEXAAMYLOSE IN SOLUTION [J].