RESONANCE RAMAN-SPECTRA OF INTERMEDIATE-SPIN FERROUS PORPHYRIN

被引：91

作者：

KITAGAWA, T

TERAOKA, J

机构：

[1] Institute for Protein Research, Osaka University, Suita, Osaka

来源：

CHEMICAL PHYSICS LETTERS | 1979年 / 63卷 / 03期

关键词：

D O I：

10.1016/0009-2614(79)80685-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The resonance Raman and absorption spectra of unligated ferrous octaethylporphyrin [Fe2+ (OEP)] and its adduct with 2-MeIm or THF were observed. The resonance Raman spectrum of Fe2+ (OEP) in CH2Cl2 displayed characteristic features of iron porphyrin with three dπ electrons, suggesting 3Eg as the intermediate-spin (S = 1) ground state. Fe2+(OEP) in THF exhibited the ferrous high spin feature like Fe2+ (OEP) (2-MeIm) in CH2Cl2. © 1979.

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页码：443 / 446

页数：4

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