A NEW CLASS OF AUI2AGI CLUSTER

被引：51

作者：

VICENTE, J ^{[1
]}

CHICOTE, MT ^{[1
]}

LAGUNAS, MC ^{[1
]}

JONES, PG ^{[1
]}

机构：

[1] TECH UNIV CAROLO WILHELMINA BRAUNSCHWEIG,INST ANORGAN & ANALYT CHEM,W-3300 BRAUNSCHWEIG,GERMANY

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1991年 / 24期

关键词：

D O I：

10.1039/c39910001730

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of the gold(I) ylide complex [(AuPPh3)2{mu-C(PPh3)(C5H4N-2)}]ClO4 with AgNO3 yields the mixed metal complex [(AuPPh3)2{mu-C(PPh3)(C5H4N-2)}{mu-Ag(eta-2-O2NO)(OClO3)], the central moiety of which consists of a loose Au2Ag cluster with metal-metal contacts ca. 3 angstrom.

引用

页码：1730 / 1731

页数：2

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