SURFACE-TENSION OF HELIUM-OXYGEN AND HELIUM-ETHANE SOLUTIONS

被引:28
作者
BAIDAKOV, VG
SULLA, II
机构
[1] Institute of Thermophysics, Urals Division of Russian Academy of Sciences, Ekaterinburg, 620219, Pervomaiskaja str. 91
关键词
ADSORPTION; CAPILLARY CONSTANT; ETHANE; GAS-SATURATED SOLUTION; HELIUM; OXYGEN; SURFACE TENSION;
D O I
10.1007/BF02093473
中图分类号
O414.1 [热力学];
学科分类号
摘要
The capillary constant has been measured, and the surface tension of gas-saturated solutions of He-O-2 and He-C2H6 has been calculated in the temperature range from the solidification temperature to approximately 0.9T(c), where T-c is the critical temperature of the solvent. Measurements have been carried out along isotherms at pressures from the saturation pressure of the pure solvent to 5 MPa. Equations approximating the baric dependence of the capillary constant and the concentration dependence of the surface tension are proposed. Adsorption is determined. The data obtained are discussed within the framework of the method of a finite-thickness layer. It is shown that for the investigated solutions the approximation of a monomolecular surface layer is not justified even at temperatures lower than the normal boiling point.
引用
收藏
页码:909 / 927
页数:19
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