CAVITY FIELD AND REACTION FIELD IN NONPOLAR FLUIDS

被引：20

作者：

CICHOCKI, B ^{[1
]}

FELDERHOF, BU ^{[1
]}

机构：

[1] RHEIN WESTFAL TH AACHEN,INST THEORET PHYS A,W-5100 AACHEN,GERMANY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1990年 / 92卷 / 10期

关键词：

D O I：

10.1063/1.458332

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We discuss the cavity field and the reaction field appearing in the Onsager-Böttcher theory of the dielectric constant of a nonpolar fluid. The ratio of both fields to the Maxwell field is determined by computer simulation for a hard-sphere fluid at six volume fractions. We find that the reaction field is reasonably well predicted by the Onsager-Böttcher theory, provided the cavity radius is adjusted to reproduce the exact value at small polarizability. The difference of the cavity field from the Lorentz local field is poorly predicted by the Onsager-Böttcher theory. © 1990 American Institute of Physics.

引用

页码：6104 / 6111

页数：8

共 24 条

[1]

BOTTCHER CJF, 1946, RECL TRAV CHIM PAY B, V65, P14

[2] The pressure-dependency of molecular polarisation on dipole-free gases and liquids. [J].

Bottcher, CJF .

PHYSICA, 1942, 9 :945-953

[3]

BOTTCHER CJF, 1973, THEORY ELECTRIC POLA, V1

[4]

BROWN WF, 1956, HANDB PHYSIK, V17, P1

[5] DIELECTRIC-CONSTANT OF POLARIZABLE, NONPOLAR FLUIDS AND SUSPENSIONS [J].

CICHOCKI, B ;

FELDERHOF, BU .

JOURNAL OF STATISTICAL PHYSICS, 1988, 53 (1-2) :499-521

[6] ELECTROSTATIC INTERACTIONS IN PERIODIC COULOMB AND DIPOLAR SYSTEMS [J].

CICHOCKI, B ;

FELDERHOF, BU ;

HINSEN, K .

PHYSICAL REVIEW A, 1989, 39 (10) :5350-5358

[7] ELECTROSTATIC SPECTRUM AND DIELECTRIC-CONSTANT OF NONPOLAR HARD-SPHERE FLUIDS [J].

CICHOCKI, B ;

FELDERHOF, BU .

JOURNAL OF CHEMICAL PHYSICS, 1989, 90 (09) :4960-4967

[8]

CLAUSIUS R, 1879, MECH BEHANDLUNG ELEK, P74

[9] EFFECTIVE DIELECTRIC-CONSTANT OF DILUTE SUSPENSIONS OF SPHERES [J].

FELDERHOF, BU ;

JONES, RB .

PHYSICAL REVIEW B, 1989, 39 (09) :5669-5677

[10]

Frohlich H., 1958, THEORY DIELECTRICS

← 1 2 3 →