SYNTHESIS OF CYCLOPALLADATED ACETYLHYDRAZONES OF PARA-METHYLACETOPOPNONE, ACETYLFERROCENE AND 2-ACETYLTHIOPHENE

被引：28

作者：

NONOYAMA, M

SUGIMOTO, M

机构：

[1] Department of Chemistry, Faculty of Science, Nagoya University, Chikusa, Nagoya

来源：

INORGANICA CHIMICA ACTA | 1979年 / 35卷 / 01期

关键词：

D O I：

10.1016/S0020-1693(00)93429-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Acetylhydrazones of p-methylacetophenone, acetylferrocene, and 2-acetylthiophene (HL) are easily cyclopalladated to give the complexes [PdClL]. A palladium-carbon bond is formed with the ortho positions of phenyl and ferrocenyl rings and with the position 3 of a thienyl ring. The complexes react with pyridine (py) to give the adducts [PdClL(py)] which have a trans-N,N, and trans-C,Cl arrangement. Some bromo analogues are also prepared and characterized. © 1979.

引用

页码：131 / 134

页数：4

共 14 条

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