IDENTIFICATION OF THE TRANSIENT BENZONITRILE N-SULFIDE BY FLASH-VACUUM PYROLYSIS AND NEUTRALIZATION-REIONIZATION MASS-SPECTROMETRY

被引：13

作者：

MAQUESTIAU, A

FLAMMANG, R

PLISNIER, M

WENTRUP, C

KAMBOURIS, P

PATON, MR

TERLOUW, JK

机构：

[1] MCMASTER UNIV,DEPT CHEM,HAMILTON L8S 4M1,ONTARIO,CANADA

[2] UNIV QUEENSLAND,DEPT CHEM,ST LUCIA,QLD 4067,AUSTRALIA

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY AND ION PROCESSES | 1990年 / 100卷

关键词：

D O I：

10.1016/0168-1176(90)85090-O

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Using a combination of flash-vacuum pyrolysis and tandem mass spectrometry, it is shown that benzonitrile N-sulfide, 1, is a stable molecule in the diluted gas phase. This result is confirmed by neutralization-reionization experiments performed on a beam of the corresponding radical cations. © 1990.

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页码：477 / 488

页数：12

相关论文

共 29 条

[11] CYCLOADDITION REACTIONS OF NITRILE SULFIDES WITH OLEFINS [J].

HOWE, RK ;

FRANZ, JE .

JOURNAL OF ORGANIC CHEMISTRY, 1978, 43 (19) :3742-3745

[12]

HOWE RK, 1973, J CHEM SOC CHEM COMM, P524

[13] NITRILE SULFIDES - SYNTHESIS OF 5-ARYL-1,2,4-THIADIAZOLE-3-CARBOXYLATES [J].

HOWE, RK ;

GRUNER, TA ;

FRANZ, JE .

JOURNAL OF ORGANIC CHEMISTRY, 1977, 42 (10) :1813-1814

[14] NITRILE SULFIDES - SYNTHESIS OF 1,2,4-THIADIAZOLES [J].

HOWE, RK ;

FRANZ, JE .

JOURNAL OF ORGANIC CHEMISTRY, 1974, 39 (07) :962-964

[15] 5-ARYL- AND 5-ALKYL-1,2,3,4-THIATRIAZOLES SYNTHETIC, SPECTROSCOPIC, AND DEGRADATIVE STUDIES [J].

LIEBER, E ;

RAO, CNR .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1963, 41 (04) :926-&

[16] MASS ANALYZED ION KINETIC-ENERGY SPECTROMETRY WITH A MODIFIED AEI-MS-902 SPECTROMETER [J].

MAQUESTIAU, A ;

VANHAVERBEKE, Y ;

FLAMMANG, R ;

ABRASSART, M ;

FINET, D .

BULLETIN DES SOCIETES CHIMIQUES BELGES, 1978, 87 (10) :765-770

[17] MODIFICATION OF A REVERSED GEOMETRY MASS-SPECTROMETER AND APPLICATIONS TO COLLISIONAL PROCESSES [J].

MAQUESTIAU, A ;

VANHAVERBEKE, Y ;

DEMEYER, C ;

FLAMMANG, R ;

PERLAUX, J .

BULLETIN DES SOCIETES CHIMIQUES BELGES, 1976, 85 (1-2) :69-78

[18]

MAQUESTIAU A, 1975, B SOC CHIM BELG, V84, P213

[19]

MAQUESTIAU A, UNPUB

[20] A NEW SYNTHESIS OF SYMMETRICAL 2,5-DIARYL-1,3,4-THIADIAZOLES [J].

MAZZONE, G ;

PUGLISI, G ;

BONINA, F ;

CORSARO, A .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1983, 20 (05) :1399-1401