SYNTHESIS AND CHARACTERIZATION OF PER-3,6-ANHYDRO CYCLODEXTRINS

被引：58

作者：

ASHTON, PR

ELLWOOD, P

STATON, I

STODDART, JF

机构：

[1] Department of Chemistry, University, Sheffield

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1991年 / 30卷 / 01期

关键词：

D O I：

10.1002/anie.199100801

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Cyclodextrin derivatives such as 1, which contain glucopyranose units in C1(4) conformation, were synthesized from per(6-O-tosyl)-beta-cyclodextrin. The pure alpha-cyclodextrin derivative (with six sugar units) was obtained from per(2.3-O-benzoyl-6-O-tosyl)-alpha-cyclodextrin. Both anhydrodextrins are potential molecular receptors in which the cavity is lined with hydroxyl groups.

引用

收藏

页码：80 / 81

页数：2

相关论文

共 23 条

[1]

BERGERON RJ, 1984, INCLUSION COMPOUNDS, V3, P391

[2] CYCLODEXTRIN CHEMISTRY - SELECTIVE MODIFICATION OF ALL PRIMARY HYDROXYL-GROUPS OF ALPHA-CYCLODEXTRINS AND BETA-CYCLODEXTRINS [J].

BOGER, J ;

CORCORAN, RJ ;

LEHN, JM .

HELVETICA CHIMICA ACTA, 1978, 61 (06) :2190-2218

[3] IMPROVED ACYLATION RATES WITHIN CYCLODEXTRIN COMPLEXES FROM FLEXIBLE CAPPING OF THE CYCLODEXTRIN AND FROM ADJUSTMENT OF THE SUBSTRATE GEOMETRY [J].

BRESLOW, R ;

CZARNIECKI, MF ;

EMERT, J ;

HAMAGUCHI, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (02) :762-770

[4] INCLUSION COMPOUNDS .20. OPTICAL ROTARY DISPERSION SPECTRA AND CONFORMATION OF GLUCOSE UNITS IN CYCLODEXTRINS [J].

CRAMER, F ;

MACKENSEN, G ;

SENSSE, K .

CHEMISCHE BERICHTE-RECUEIL, 1969, 102 (02) :494-+

[5] SYNTHESIS OF CHEMICALLY MODIFIED CYCLODEXTRINS [J].

CROFT, AP ;

BARTSCH, RA .

TETRAHEDRON, 1983, 39 (09) :1417-1474

[6] INTERGLUCOSYL ATTACK OF HYDROXYL GROUP TO EPOXY RING OF 2A,3A-ANHYDRO-(2AS)-ALPHA-CYCLODEXTRIN - SELECTIVE PREPARATION OF 3A,2B-ANHYDRO-ALPHA-CYCLODEXTRIN [J].

FUJITA, K ;

TAHARA, T ;

SASAKI, H ;

EGASHIRA, Y ;

SHINGU, T ;

IMOTO, T ;

KOGA, T .

CHEMISTRY LETTERS, 1989, (05) :917-920

[7] SPECIFIC PREPARATION AND STRUCTURE DETERMINATION OF 3A,3C,3E-TRI-O-SULFONYL-BETA-CYCLODEXTRIN [J].

FUJITA, K ;

TAHARA, T ;

YAMAMURA, H ;

IMOTO, T ;

KOGA, T ;

FUJIOKA, T ;

MIHASHI, K .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (03) :877-880

[8] PREPARATION OF 3A,6A-ANHYDRO-BETA-CYCLODEXTRIN AND ITS TAKA AMYLOLYSIS [J].

FUJITA, K ;

YAMAMURA, H ;

IMOTO, T ;

TABUSHI, I .

CHEMISTRY LETTERS, 1988, (03) :543-546

[9] REGIOSPECIFICALLY BIFUNCTIONAL CYCLODEXTRINS HAVING 2 AMINO-GROUPS ON SECONDARY HYDROXYL SIDE [J].

FUJITA, K ;

EGASHIRA, Y ;

IMOTO, T ;

FUJIOKA, T ;

MIHASHI, K ;

TAHARA, T ;

KOGA, T .

CHEMISTRY LETTERS, 1989, (03) :429-432

[10] SELECTIVE HALOGENATION AT PRIMARY POSITIONS OF CYCLOMALTOOLIGOSACCHARIDES AND A SYNTHESIS OF PER-3,6-ANHYDRO CYCLOMALTOOLIGOSACCHARIDES [J].

GADELLE, A ;

DEFAYE, J .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (01) :78-80