SYNTHESIS AND STRUCTURE OF [(ETA-5-C5ME5)RU(MU-NHPH)]2, AN ELECTRON-DEFICIENT RUTHENIUM AMIDE COMPLEX

被引:42
作者
BLAKE, RE [1 ]
HEYN, RH [1 ]
TILLEY, TD [1 ]
机构
[1] UNIV CALIF SAN DIEGO,DEPT CHEM 0506,9500 GILMAN DR,LA JOLLA,CA 92093
基金
美国国家科学基金会;
关键词
D O I
10.1016/S0277-5387(00)83329-X
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The reaction of [Cp*Ru(mu-3-Cl)]4 (CP* = eta-5-C5Me5) with NaNHPh in THF affords the blue anilide complex [Cp*Ru(mu-NHPh)]2. Characterization of this complex by X-ray crystallography reveals a folded dimeric structure with bridging anilide ligands.
引用
收藏
页码:709 / 710
页数:2
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