EXCITED-STATE ENERGY OF (3MLCT)RU(BPY)-3(2+) BY TIME-RESOLVED THERMAL LENS AND PHOTOACOUSTIC METHODS IN AQUEOUS-SOLUTIONS

被引：14

作者：

SONG, XQ

ENDICOTT, JF

机构：

[1] Department of Chemistry, Wayne State University, Detroit

来源：

CHEMICAL PHYSICS LETTERS | 1993年 / 204卷 / 5-6期

关键词：

D O I：

10.1016/0009-2614(93)89176-I

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The time-resolved thermal lens and the pulsed photoacoustic techniques have been used to determine the thermally averaged charge transfer excited state energy of Ru(bpy)32+ in ambient aqueous solutions. The averaged excited state energy of ((3MLCT)Ru(bpy)32+) was found to be (16.8 +/- 0.2) x 10(3) cm-1 by the photoacoustic method and (17.0 +/- 0.6) x 10(3) cm-1 by the thermal lens method. These measurements indicate that the difference between the effective molar volumes of the ground and charge transfer excited states is very small.

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页码：400 / 406

页数：7

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