IONIC HYDROGEN-BOND AND DEPROTONATION OF CATIONIC HYDRIDE [(ETA-5-C5ME5)2OSH]+A-

被引：5

作者：

EPSTEIN, LM

SHUBINA, ES

KRYLOV, AN

KREINDLIN, AZ

RYBINSKAYA, MI

机构：

[1] A.N. Nesmeyanov Institute of Organo-Element Compounds, the Russian Academy of Science, Moscow, Vavilov str., 28

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 460卷 / 01期

关键词：

D O I：

10.1016/0022-328X(93)80362-F

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ionic hydrogen bond formation by protonated metallocene and the anion, [(eta5-C5Me5)2OsH]+...-OOCCF3, as the first stage of deprotonation was discovered by IR spectra in low polar solvents. The equilibrium between the molecular and ionic hydrogen-bonded complexes, (eta5-C5Me5)2OS...HOOCCF3, formed after proton transfer is investigated. The structure of the ion pairs [(eta5-C5Me5)2OsH]+A- (A = BF4, PF6, CF3SO3) in the solid state and solution are discussed.

引用

页码：87 / 89

页数：3

共 4 条

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[3] INTERACTION BETWEEN [(ETA(5)-C5ME5)2OSH]+PF6- AND NITROGEN OR OXYGEN BASES - HYDROGEN-BONDS OF THE TYPE [OSH]+ ... B
EPSTEIN, LM
SHUBINA, ES
KRYLOV, AN
KREINDLIN, AZ
RYBINSKAYA, MI
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 447 (02) : 277 - 280
[4] SHUBINA ES, 1993, IN PRESS J MOL STRUC

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