VOLTAMMETRY AT LEAD DIOXIDE ELECTRODE - ANODIC EDTA CURRENTS

被引：15

作者：

TALLANT, DR

HUBER, CO

机构：

[1] Department of Chemistry, Surface Studies Laboratory, University of Wisconsin-Milwaukee, Miswaukee

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1968年 / 18卷 / 04期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0368-1874(68)89026-4

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

In the presence of 10-5 M or larger concentrations of EDTA in acetate buffer, a lead dioxide electrode exhibits relatively high anodic currents at positive potentials. The mechanism for this electrode reaction was investigated. The results of experi- ments including manual current -voltage plots, u.v. absorption, coulometry, chronopo- tentiometry, and linear sweep voltammetry are presented. A mechanism is suggested which involves oxidation of non-stoichiometric (defect) lead species in the electrode lattice by electroinductive coordination effects of EDTA and a catalytic electrode reaction mechanism. © 1968.

引用

页码：413 / &

共 14 条

[1] CONDITIONS FOR THE FORMATION OF A OR B LEAD DIOXIDE DURING THE ANODIC OXIDATION OF LEAD
BAKER, RA
[J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1962, 109 (04) : 337 - 338
[2] BECK MT, 1961, CHEM ANALYST, V50, P14
[3] CHACTIER P, 1964, COMPT REND, V258, P4495
[4] IKARI S, 1960, DENKI KAGAKU, V28, P596
[5] KABANOV BN, 1964, ELECTROCHIM ACTA, V9, P1197
[6] MACHTING.M, 1961, ANN CHIM FRANCE, V6, P395
[7] MAGNELI A, 1963, ARK KEMI, V21, P407
[8] THEORY OF STATIONARY ELECTRODE POLAROGRAPHY - SINGLE SCAN + CYCLIC METHODS APPLIED TO REVERSIBLE IRREVERSIBLE + KINETIC SYSTEMS
NICHOLSON, RS
SHAIN, I
[J]. ANALYTICAL CHEMISTRY, 1964, 36 (04) : 706 - &
[9] Ruetschi P., 1963, ELECTROCHIM ACTA, V8, P333
[10] TALLANT DR, 1968, J ELECTRONANAL CHEM, V18, P421

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