SYNTHESES OF [1-(ALKYLTHIO)]-AND (1-MERCAPTO) CYCLOALKANEPHOSPHONIC ESTERS BY REACTIONS OF CYCLOALKANETHIONES WITH TRIALKYL PHOSPHITES

被引：19

作者：

YONEDA, S ^{[1
]}

KAWASE, T ^{[1
]}

YOSHIDA, Z ^{[1
]}

机构：

[1] KYOTO UNIV,DEPT SYNTHET CHEM,KYOTO 606,JAPAN

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1978年 / 43卷 / 10期

关键词：

D O I：

10.1021/jo00404a029

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cycloalkanethiones reacted with trialkyl phosphites to give [1-(alkylthio)]- and/or (1-mercapto)cycloalkanephosphonic esters. The reaction mechanism is discussed in terms of a concerted one via the betaine intermediate. These sulfur-containing esters are easily converted to cycloalkanephosphonic esters in good yields by Raney nickel treatment. © 1978, American Chemical Society. All rights reserved.

引用

页码：1980 / 1985

页数：6

共 30 条

[1] TRIALKYL PHOSPHITES - NOVEL RING-OPENING REACTIONS WITH DIMETHYLKETENE DIMERS [J].