REACTION OF H2OS5(CO)15 WITH NUCLEOPHILIC-REAGENTS

被引：31

作者：

JOHN, GR ^{[1
]}

JOHNSON, BFG ^{[1
]}

LEWIS, J ^{[1
]}

NELSON, WJ ^{[1
]}

MCPARTLIN, M ^{[1
]}

机构：

[1] N LONDON POLYTECH,LONDON,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 171卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)88075-4

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of H2Os5(CO)15 with nucleophiles Y leads either to deprotonation (Y = OH- or Me-) or addition (Y = I-, P(OMe)3, or CO). The geometrical consequences of these reactions are discussed. © 1979.

引用

页码：C14 / C20

页数：7

共 6 条

[1] PREPARATION, PROPERTIES AND STRUCTURE OF IRON CARBONYL CARBIDE FE5(CO)15C [J].

BRAYE, EH ;

WAMPLER, DL ;

DAHL, LF ;

HUBEL, W .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1962, 84 (24) :4633-&

[2]

EADY CR, 1976, J CHEM SOC CHEM COMM, P271

[3] CHEMISTRY OF POLYNUCLEAR COMPOUNDS .29. PRODUCTS OF REACTION OF TRIRUTHENIUM AND TRIOSMIUM DODECACARBONYLS WITH WATER [J].

EADY, CR ;

JOHNSON, BFG ;

LEWIS, J .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1977, (09) :838-844

[4] SYNTHESIS AND MOLECULAR-STRUCTURE OF [OS5(CO)15POME] [J].

FERNANDEZ, JM ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1978, (23) :1015-1016

[5] DI-MU-HYDRIDO-HEXADECACARBONYLPENTAOSMIUM [J].

GUY, JJ ;

SHELDRICK, GM .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1978, 34 (MAY) :1725-1727

[6]

KELLER E, 1977, ANGEW CHEM, V89, P738

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