THE STABILITY OF BUCKMINSTERFULLERENE (C-60) - EXPERIMENTAL-DETERMINATION OF THE HEAT OF FORMATION

被引：89

作者：

BECKHAUS, HD

RUCHARDT, C

KAO, M

DIEDERICH, F

FOOTE, CS

机构：

[1] UNIV FREIBURG,INST ORGAN CHEM & BIOCHEM,ALBERTSTR 21,W-7800 FREIBURG,GERMANY

[2] UNIV CALIF LOS ANGELES,DEPT CHEM & BIOCHEM,LOS ANGELES,CA 90024

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1992年 / 31卷 / 01期

关键词：

D O I：

10.1002/anie.199200631

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The standard enthalpy of formation of crystalline buckminsterfullerene (C60) is 544.99 +/- 1.35 kcal mol-1 which corresponds to 9.08 +/- 0.02 kcal mol-1 per C atom. This follows from the calorimetric determination of the heat of combustion of extremely pure C60. Of the several theoretically predicted heats of formation, the value calculated with the MM3 force field (DELTA-H(f)0 (g) = 570 kcal mol-1) shows the best agreement with the experimental data.

引用

页码：63 / 64

页数：2

共 27 条

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