N-FLUOROQUINUCLIDINIUM TRIFLUOROMETHANE-SULFONATE (TRIFLATE) - A NOVEL ELECTROPHILIC FLUORINATING AGENT

被引：4

作者：

BANKS, RE

PRITCHARD, RG

SHARIF, I

机构：

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1993年 / 49卷

关键词：

D O I：

10.1107/S0108270193003646

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The N-F bond length of 1.407 (6) angstrom in the title molecule is close to the value of 1.37 (2) angstrom found in 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) [Banks, Sharif & Pritchard (1993). Acta Cryst. C49, 492-495]. Both these bonds are substantially longer than those in NF4+.BF4-, which range from 1.265 (9) to 1.321 (10) angstrom [Christie, Lind, Tborup, Russell, Fawcett & Bau (1988). Inorg. Chem. 27, 2450-2454].

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页码：1806 / 1807

页数：2

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