CHARACTERIZATION OF DEHYDROCHLORINATED POLY(VINYLIDENE CHLORIDE) AND THE SHOCK-COMPRESSED MATERIAL

被引：11

作者：

KOMATSU, T

NOMURA, M

KAKUDATE, Y

FUJIWARA, S

HEIMANN, RB

机构：

[1] NATL INST MAT & CHEM RES, TSUKUBA, IBARAKI 305, JAPAN

[2] FREIBERG UNIV MIN & TECHNOL, CHAIR TECH MINERAL, D-09596 FREIBERG, GERMANY

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1995年 / 196卷 / 09期

关键词：

D O I：

10.1002/macp.1995.021960925

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dehydrochlorinated poly(vinylidene chloride) proved to be a conjugated polyene-polyene polymer. Shock compression of the polymer formed a large portion of graphite and trace amounts of diamond and of an unknown carbon. The unknown carbon belongs to the hexagonal crystal system and possesses the cell dimension a(0) = 0.338 nm. A comparison with known carbynes was made in terms of the crystalline parameters.

引用

收藏

页码：3031 / 3040

页数：10

相关论文

共 25 条

[1] ONE-DIMENSIONAL CONJUGATED CARBYNE - SYNTHESIS AND PROPERTIES [J].

AKAGI, K ;

NISHIGUCHI, M ;

SHIRAKAWA, H ;

FURUKAWA, Y ;

HARADA, I .

SYNTHETIC METALS, 1987, 17 (1-3) :557-562

[2] ABSORPTION SPECTRA .5. THE ULTRAVIOLET AND VISIBLE SPECTRA OF CERTAIN POLYENE ALDEHYDES AND POLYENE AZINES [J].

BLOUT, ER ;

FIELDS, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1948, 70 (01) :189-193

[3] HEXAGONAL DIAMOND - A NEW FORM OF CARBON [J].

BUNDY, FP ;

KASPER, JS .

JOURNAL OF CHEMICAL PHYSICS, 1967, 46 (09) :3437-&

[4] SYNTHETIC APPROACHES TOWARD MOLECULAR AND POLYMERIC CARBON ALLOTROPES [J].

DIEDERICH, F ;

RUBIN, Y .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (09) :1101-1123

[5] ALL-CARBON MOLECULES - EVIDENCE FOR THE GENERATION OF CYCLO[18]CARBON FROM A STABLE ORGANIC PRECURSOR [J].

DIEDERICH, F ;

RUBIN, Y ;

KNOBLER, CB ;

WHETTEN, RL ;

SCHRIVER, KE ;

HOUK, KN ;

LI, Y .

SCIENCE, 1989, 245 (4922) :1088-1090

[6] SILYLATION AS A PROTECTIVE METHOD FOR TERMINAL ALKYNES IN OXIDATIVE COUPLINGS - GENERAL SYNTHESIS OF PARENT POLYYNES - H(C=C)NH (N=4-10, 12) [J].

EASTMOND, R ;

WALTON, DRM ;

JOHNSON, TR .

TETRAHEDRON, 1972, 28 (17) :4601-&

[7]

KASATOCH.VI, 1967, DOKL AKAD NAUK SSSR+, V177, P358

[8]

KASATOCHKIN VI, 1974, DOKL AKAD NAUK, V214, P84

[9] CARBYNOID SPECIES IN ELECTROCHEMICAL POLYMERIC CARBON [J].

KAVAN, L ;

DOUSEK, FP .

SYNTHETIC METALS, 1993, 58 (01) :63-72

[10]

KORSHAK VV, 1961, DOKL AKAD NAUK SSSR+, V136, P1342