SYNTHESIS AND PROPERTIES OF SEVERAL ANNELATED 1,5-DI-TRANS-[10]ANNULENES

被引:4
作者
BINDRA, AP
ELIX, JA
SARGENT, MV
机构
[1] Chemistry Department, Australian National University, Canberra, ACT
[2] University Chemical Laboratory, University of Kent, Kent, Canterbury
关键词
D O I
10.1071/CH9691449
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Di-trans-1,2:3,4-dibenzo[7,8-c]furo[10]annulene (VI) and di-trans- 1,2:3,4-dibenzo-7,8-(3′,6′-epoxy-4′,5′- dimethoxycarbonyl)cyclo- hexeno[10]annulene (VII) have been synthesized. As a result of the steric interference of the internal hydrogen atoms, the former compound could be separated into two conformational isomers. Neither (VI) nor (VII) possessed a delocalized ten π-electron system. © 1969, CSIRO. All rights reserved.
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页码:1449 / &
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