SYNTHESIS AND REACTIVITY OF PALLADIUM AND PLATINUM COMPLEXES CONTAINING THE BIS(DIPHENYLPHOSPHINO)METHANIDE LIGAND

被引：19

作者：

FORNIES, J

NAVARRO, R

URRIOLABEITIA, EP

机构：

[1] Departamento de Quimica Inorganica. Instituto de Ciencia de Materiales de Aragon, Universidad de Zaragoza, C.S.I.C.

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 390卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85037-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of general formulae [M(C6X5)(Ph2PCHPPh2)(L)] (M Pd, Pt; X F, Cl; L PR3, dppm(Ph2PCH2PPh2)) have been obtained either by reaction of MCl(C6F5)(PR3)2 with dppm and NaH or with dppm-Li or reaction of [M(C6F5)(dppm)(PR3)](ClO4) with NaH. The complexes M(C6X5)(acac)(L) react with dppm to give analogous ddppm {[Ph2PCHPPh2]-} derivatives. Treatment of these complexes with HBF4 gives of the corresponding dppm cationic derivatives. The complexes have been characterized by IR, 19F NMR, and 31P(1H) NMR spectroscopy. © 1990.

引用

页码：257 / 265

页数：9

共 23 条

[1] THE RELATIVE AFFINITIES OF LIGAND ATOMS FOR ACCEPTOR MOLECULES AND IONS
AHRLAND, S
CHATT, J
DAVIES, NR
[J]. QUARTERLY REVIEWS, 1958, 12 (03): : 265 - 276
[2] C-ALKYLATION OF CARBANIONS DERIVED FROM [PTHALOGEN2-(PH2PCH2PPH2)], [PDHALOGEN2-(PH2PCH2PPH2)]
ALJIBORI, S
SHAW, BL
[J]. INORGANICA CHIMICA ACTA-LETTERS, 1982, 65 (04): : L123 - L124
[3] SYNTHESIS AND A CRYSTAL-STRUCTURE ANALYSIS OF MIXED "BIS(PHOSPHINO)METHANIDE-PHOSPHONIUM BIS-(METHYLIDE) COMPLEXES OF NICKEL, PALLADIUM, AND PLATINUM
BASSETT, JM
MANDL, JR
SCHMIDBAUR, H
[J]. CHEMISCHE BERICHTE-RECUEIL, 1980, 113 (03): : 1145 - 1152
[4] ACIDITIES OF CARBON ACIDS .4. KINETIC VS EQUILIBRIUM ACIDITIES AS MEASURES OF CARBANION STABILITIES - RELATIVE EFFECTS OF PHENYLTHIO, DIPHENYLPHOSPHINO, AND PHENYL GROUPS
BORDWELL, FG
MATTHEWS, WS
VANIER, NR
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1975, 97 (02) : 442 - 443
[5] BROWN MP, 1982, J ORGANOMET CHEM, V236, pC33
[6] FORMATION OF THE NOVEL BIS(DIPHENYLPHOSPHINO)METHANIDE LIGAND BY DEPROTONATION OF A COORDINATED BIS(DIPHENYLPHOSPHINO)METHANE - CRYSTAL AND MOLECULAR-STRUCTURE OF CHLORO-TRIETHYLPHOSPHINE-BIS(DIPHENYLPHOSPHINO)METHANOPLATINUM(II)
BROWNING, J
BUSHNELL, GW
DIXON, KR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 198 (01) : C11 - C14
[7] NEW TYPE OF STABLE ORGANOMETALLIC COPPER COMPLEX - PROPERTIES AND STRUCTURE OF PRODUCT OF REACTION OF ARYLCOPPER COMPOUNDS WITH BIS(DIPHENYLPHOSPHINO)METHANE
CAMUS, A
MARSICH, N
NARDIN, G
RANDACCI.L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 60 (01) : C39 - C42
[8] CASABO J, 1975, INORG CHIM ACTA, V11, P5
[9] FORMATION OF A BRIDGED VINYLIDENEDI-IRON COMPLEX BY NUCLEOPHILIC-ATTACK ON A CARBONYL LIGAND OF [FE2(CO)4(ETA-C5H5)2], AND THE SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [(OC)3FE(MU-PH2PCHPPH2)FEH(CO)3]
DAWKINS, GM
GREEN, M
JEFFERY, JC
SAMBALE, C
STONE, FGA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1983, (03): : 499 - 506
[10] NEUTRAL AND CATIONIC ORTHOPALLADATED (CN) COMPLEXES (CN = PHENYLAZOPHENYL, DIMETHYLBENZYLAMINE, 8-METHYLQUINOLINE, 2-METHOXY-3-N,N-DIMETHYLAMINOPROPYL)
FORNIES, J
NAVARRO, R
SICILIA, V
[J]. POLYHEDRON, 1988, 7 (24) : 2659 - 2665

← 1 2 3 →