RING SIZE EFFECTS ON SOME C-13-NMR, P-31-NMR AND PT-195-NMR PARAMETERS IN THE SERIES [PH2P(CH2)NPH2]PT(CH3)2

被引：79

作者：

HIETKAMP, S ^{[1
]}

STUFKENS, DJ ^{[1
]}

VRIEZE, K ^{[1
]}

机构：

[1] UNIV AMSTERDAM,JH VANTHOFF INST,ANORGAN CHEM LAB,AMSTERDAM,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 169卷 / 01期

关键词：

D O I：

10.1016/S0022-328X(00)81461-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The 31P, 13C, and 195Pt NMR spectra of the compounds {Ph2P(CH2)nPPh2}Pt(CH2)2 were studied and compared with the spectra of the acyclic analogue, cis-(Ph2PCH3)2Pt(CH3)2. Comparison with structural data showed that irregularities in the NMR parameters can be explained on the basis of the existence of angle strain for four-membered but not for five-membered rings. © 1979.

引用

页码：107 / 113

页数：7

共 15 条

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