VIBRATIONAL-SPECTRA AND NORMAL COORDINATE ANALYSIS OF DIFLUOROPHOSPHINE-D0 AND DIFLUOROPHOSPHINE-D1

被引：10

作者：

DURIG, JR

ZOZULIN, AJ

ODOM, JD

STREUSAND, BJ

机构：

[1] Department of Chemistry, University of South Carolina, Columbia, South Carolina

来源：

JOURNAL OF RAMAN SPECTROSCOPY | 1979年 / 8卷 / 05期

关键词：

D O I：

10.1002/jrs.1250080509

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

The Raman and infrared spectra of difluorophosphine and difluorophosphine‐d1 in the gaseous and solid phases from 100 to 3000 cm−1 have been recorded. The six fundamental frequencies have been assigned on the basis of group frequencies, depolarization ratios, band types and isotopic shifts. A normal coordinate analysis was carried out. Very little mixing was found to occur between the normal modes. Thermodynamic functions were calculated from the observed frequencies and previously reported moments of inertia. Copyright © 1979 Heyden & Son Ltd.

引用

页码：259 / 264

页数：6

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